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      4. Abrasive Technology

      Abrasive Technology

      Abrasive technology -  basics:

      CGW's advanced abrasive technology based on years of experience and ongoing research insures  our unconditionally commitment to innovation and to the quality and safety of our products.

      Bonded abrasives are made by incorporating abrasives grains into a matrix, which can be resin and fillers or vitreous materials. Usually, such abrasives contain porosity which helps to control the thermal aspects of the process.
      Coated abrasives are abrasive grains incorporated or cloth backing. The formulation and choice of additives are usually a closely guarded secret of the manufacturer. In order to choose the right wheel material and structure several quest ions must be asked:

      • Type of use: cutting, grinding, polishing etc 
      • Type of article to be ground and materials: Nickel alloy blade, metal cylinder etc. 
      • Type of abrasive grain needed: Aluminum oxide, boron nitride etc.
      • Type of specific physical property: porous, compacted etc.
      • Type of bonding: verified, resin etc.
      • Type of fabrication process: Cold or hot press etc.
      • The structure of the bonded abrasives is described in terms of proportions of abrasive phase, the volume of porosity and the volume fraction of the bond as described in grinding wheels phase diagram.

      Each axis represents 100% of one component with the opposite side corresponding to 0% and intermediate percentages represented by the fractional distance from the side to the axis. Actual wheels compositions do not cover the whole composition range represented by the phase diagram but are restricted to a limit range by technological and practical  factors.



                 

       

      Abrasive technology - Grains:

      Abrasive grains are the tools of the grinding and cutting process. In the past abrasives grains were derived from natural minerals,
      such as emery, quartz sand, and so on, today, the industry is almost entirely dependant upon synthetic grains, which are far more
      consistent and cost-effective. Some physical properties of the most important abrasives materials are Summarized in Table 1.

      Table 1: Physical properties of main abrasive grains

               

      Property

       Aluminum Oxide 

       Silicon Carbide 

       Boron Nitride 

       Diamond 

      Crystal Structure

      Hexagonal

      Hexagonal

      Cubic

      Cubic

      Density (g/cm3)

      3.98

      3.22

      3.48

      3.52 

      Melting Point (C)

      2040

      ~2830

      ~3200

      ~3700

      Knoop Hardnes
      (kg/mm2)

      2100

      2400

      4700

      8000


      The characteristics of the grains as size, shape, strength, friability are important and control the wheel's performance as the matrix material.
      Table 2: Typical characteristics of abrasive grains.



           

      Grain

       Knoop Hardness kg/mm2  

       Friability Index 

      Aluminum Oxide

      Pink/red (3% Cr)

      2260 

      65.0

      White

      2120

      56.6

      Single Crystal

      2280

      47.7

      Regular

      2040

      35.6

      40% ZrO2

      1460

      7.9

      Sintered

      1370

      6.5

      Silicon Carbide

      Green

      2840

      62.5

      Black

      2680

      57.2

       

      Fused Aluminum Oxide and its derivatives: Aluminum Oxide is derived from Bauxite in an industrial high-energy process. During the melting stage the crystalline structure as well as the chemistry can be controlled and results in pure crystal Aluminum oxide, white fused Aluminum oxide (low Iron and Silica content), Semi-friable Aluminum oxide (low titania levels), Monocrystalline  Aluminum oxide  (strong cutting edges and a high compressive strength) and Red and Pink Aluminum Oxide (high Chrome levels). Applications: For grinding high tensile strength materials, as well as rough grinding , deburring, snagging, cutting and fettling of low-alloy, ferrous materials (Regular Aluminum Oxide). For grinding hardened and high alloy steels up to 62 Rc (White Aluminum Oxide).  For high-alloy steels, grinding operations with high form and dimensional accuracy requirements (Monocrystalline  Aluminum oxide). Aluminum Oxide-Zirconia: The production of aluminum-oxide Zirconia grains involves similar equipment and process to that of standard Aluminum Oxide. The presence of Zirconia phase and its crystal size can improve the toughness of the grain compared to white or brown Aluminum Oxide.



      Applications: Used in steel mills and foundries. Sol-Gel Aluminum Oxide and derivatives: Aluminum Oxide produced by the sol-gel technique has very fine crystals and therefore retains sharp cutting edge as the material wear. One of the disadvantages of the Sol-gel Aluminum Oxide is it low thermal stability with respect to fused Aluminum Oxide. Applications: Used on both ferrous and non-ferrous materials. Silicon Carbide: The material is harder than Aluminum Oxide, but it is usually much more friable. The manufacturing process  makes controlled use of high energy to obtain green or black silicon carbide. The black silicon carbide has a higher impurity content than the green grain. Applications: For grinding low tensile materials like cast iron, non-ferrous and non-metallic. Resin based: Phenolic thermosetting resins are still by far the most important organic bonds for grinding and cutting wheels. The properties of the bond can be varied to give elastic or thermal properties by incorporating plasticizers or fillers. Compared to vitrified wheels, resin-bonded wheels are much more resistant to shock and loading and heavy-duty use. They are therefore, more popular in snagging operations and for cut-off wheels where uncontrolled lateral stresses can be very high. When extremely high strength is required, for example in high-speed operations (>100 meter per second surface speed), then the resin may be further reinforce with glass fiber. There are limitations, however, in terms of temperature that can be permitted at grinding/cutting surface. Also, resins wheels can be attacked by alkaline grinding fluids. 

      Vitreous based: Compared to resin-bonded wheels, those with vitrified bonds can withstand much higher temperatures, but they are often significantly less tough. Also, the vitrified wheels are unaffected by water, acids and oils. T he essential raw materials are clay, feldspar and glass frits, similar to those in the ceramics whitewares sector. The vitreous bond phase is made during the firing of the wheel at high temperature up to 1250 degrees C and higher. Fillers: Fillers are added into the mixture for different purposes as described in the table below: Table 3: Fillers Type and functionality

           

      Function

      Description

      Filler Material

      Production of pores

      Temporary

      Semi-permanent

      Permanent

      Nut shell, Wax, Naphthalene

      Graphite, coke

      Glass balls, Spherical aluminum oxide

      Active grinding effects

      Lubricants

      Cryolite, Chlorides, Iron Pyrites, Phosphates

      Production aids

      Curing aids

      Pressing aids

      Calcium Oxide, Magnesium Oxide

      Stearates, Wax


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